Chimica | ADVANCED PHYSICAL CHEMISTRY

cod. 0522300009

ADVANCED PHYSICAL CHEMISTRY

	0522300009
	DIPARTIMENTO DI CHIMICA E BIOLOGIA "ADOLFO ZAMBELLI"

	CHEMISTRY
	2015/2016

PERCORSO COMUNE

	OBBLIGATORIO
	YEAR OF COURSE 1
	YEAR OF DIDACTIC SYSTEM 2010
	PRIMO SEMESTRE

TEACHING UNITS

	SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
1	CHIMICA FISICA SUPERIORE MODULO A
	CHIM/02	7	56	LESSONS	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
2	CHIMICA FISICA SUPERIORE MODULO B
	CHIM/02	2	24	EXERCISES	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
	CHIM/02	3	36	LAB	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS

PROFESSORS

	ANDREA PELUSO1 T Curriculum
	GUGLIELMO MONACO2 Curriculum

	Objectives
	ACHIEVE KNOWLEDGE AND UNDERSTANDING OF THE LAWS OF THE MICROSCOPIC MATTER; APPLY THEIR KNOWLEDGE AND UNDERSTANDING TO CHEMICAL PROBLEMS IN A PROFESSIONAL WAY; ACHIEVE ABILITY TO COMMUNICATE INFORMATION, NEW IDEAS AND SOLUTIONS. ACHIEVE THE ABILITY OF INTEPRETING RELEVANT DATA AND OF DESIGNING AN EXPERIMENT. DEVELOP LEARNING SKILLS NECESSARY FOR THEIR PROFESSIONAL LIFE.

	Prerequisites
	CLASSICAL PHYSICS; DIFFERENTIAL EQUATIONS AND LINEAR ALGEBRA

	Contents
	PROBABILITY AMPLITUDES; SUPERPOSITION PRINCIPLE; FERMIONS AND BOSONS; SCHROEDINGER EQUATIONS. MEASUREMENTS IN QUANTUM MECHANICS; STERN-GERLACH EXPERIENCE. THE TWO STATE MODEL; VARIATIONAL THEOREM AND PERTURBATION THEORY. MULTIELECTRON ATOMS; SPECTROSCOPIC TERMS. BORN-OPPHENEIMER THEOREM, THE CHEMICAL BOND; THE MO AND VB METHODS. TIME-DEPENDENT PERTURBATION THEORY; TRANSITION PROBABILITIES; ROTATIONAL, VIBRATIONAL AND ELECTRONIC SPECTROSCOPIES. USE OF THE FOURIER TRANSFORM IN VIBRATIONAL SPECTROSCOPY; PERTURBATIVE APPROACH TO VAN DER WAALS INTERACTIONS. LABORATORY EXPERIENCES: VIBROROTATIONAL SPECTRUM OF HCL; ROTATIONAL SPECTRUM OF A SYMMETRIC TOP; HUECKEL METHOD; DETERMINATION OF A BOND ENERGY LINK: VIBRONIC SPECTRUM OF MOLECULAR IODINE; NUMERICAL APPLICATION OF THE VARIATIONAL METHOD FOR DETERMINING EIGENVALUES AND EIGENFUNCTIONS OF A ONE-DIMENSIONAL ANHARMONIC POTENTIAL; APPLICATIONS OF STATISTICAL TESTS FOR SELECTION OF LINEAR MODELS.

PROBABILITY AMPLITUDES; SUPERPOSITION PRINCIPLE; FERMIONS AND BOSONS; SCHROEDINGER EQUATIONS. MEASUREMENTS IN QUANTUM MECHANICS; STERN-GERLACH EXPERIENCE. THE TWO STATE MODEL; VARIATIONAL THEOREM AND PERTURBATION THEORY. MULTIELECTRON ATOMS; SPECTROSCOPIC TERMS. BORN-OPPHENEIMER THEOREM, THE CHEMICAL BOND; THE MO AND VB METHODS. TIME-DEPENDENT PERTURBATION THEORY; TRANSITION PROBABILITIES; ROTATIONAL, VIBRATIONAL AND ELECTRONIC SPECTROSCOPIES.
USE OF THE FOURIER TRANSFORM IN VIBRATIONAL SPECTROSCOPY; PERTURBATIVE APPROACH TO VAN DER WAALS INTERACTIONS.
LABORATORY EXPERIENCES: VIBROROTATIONAL SPECTRUM OF HCL; ROTATIONAL SPECTRUM OF A SYMMETRIC TOP; HUECKEL METHOD; DETERMINATION OF A BOND ENERGY LINK: VIBRONIC SPECTRUM OF MOLECULAR IODINE; NUMERICAL APPLICATION OF THE VARIATIONAL METHOD FOR DETERMINING EIGENVALUES AND EIGENFUNCTIONS OF A ONE-DIMENSIONAL ANHARMONIC POTENTIAL; APPLICATIONS OF STATISTICAL TESTS FOR SELECTION OF LINEAR MODELS.

	Teaching Methods
	LECTURES AND EXCERSICES

	Verification of learning
	ORAL EXAMINATION CONCERNING LABORATORY EXPERIENCES AND THE APPLICATION OF THE MOST IMPORTANT PRINCIPLES TO CHEMICAL PROBLEMS

	Texts
	FRENCH, TAYLOR, AN INTRODUCTION TO QUANTUM PHYSICS, MIT PRESS 1985; FEYNMANN R. LEZIONI DI FISICA, VOL 3; LEVINE I.N. QUANTUM CHEMISTRY; HOLLAS, MODERN SPECTROSCOPY, JOHN WILEY & SONS

BETA VERSION Data source ESSE3 [Ultima Sincronizzazione: 2016-09-30]