Chimica | PHYSICAL METHODS IN INORGANIC CHEMISTRY

cod. 0522300017

PHYSICAL METHODS IN INORGANIC CHEMISTRY

	0522300017
	DIPARTIMENTO DI CHIMICA E BIOLOGIA "ADOLFO ZAMBELLI"

	CHEMISTRY
	2015/2016

PERCORSO COMUNE

	YEAR OF DIDACTIC SYSTEM 2010
	SECONDO SEMESTRE

TEACHING UNITS

	SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
	CHIM/03	6	48	LESSONS	SUPPLEMENTARY COMPULSORY SUBJECTS

	Objectives
	KNOWLEDGE AND UNDERSTANDING: THIS COURSE AIMS TO PROVIDE THE BASIC KNOWLEDGE OF SYMMETRY AND SPECTROSCOPY AND TO PROVIDE THE METHODS TO GET INFORMATION FROM SEVERAL SPECTROSCOPIC TECHNIQUES FOR THE CHARACTERIZATION OF INORGANIC AND METALLORGANIC COMPOUNDS APPLYING KNOWLEDGE AND UNDERSTANDING: AT THE END OF THE COURSE THE STUDENT WILL BE ABLE TO SOLVE PROBLEMS OF STRUCTURAL ASSIGNMENT BY SPECTROSCOPIC ANALYSIS. MAKING JUDGMENTS: STUDENTS ARE ENCOURAGED TO LEARN IN A CRITICAL MANNER. DURING THE COURSE EXERCISES WILL PROPOSED. THE TEACHER WILL ENCOURAGE THE STUDENTS WITH QUESTIONS AND DISCUSSIONS ON THE MATTERS OF COURSE. COMMUNICATION SKILLS: THE TEACHER WILL PROMOTE THE ABILITY TO EXPOSE IN A CLEAR AND STRICT WAY THE CONCEPTS LEARNED DURING THE LESSONS. AT THE END OF THE COURSE THE STUDENT MUST BE ABLE TO PROPERLY EXPLAIN THE ARGUMENTS OF THE COURSE. LEARNING SKILLS : THE STUDENTS WILL BE PROVIDED WITH APPROPRIATE ADVICE AND INCENTIVES FOR AN ACTIVE PARTICIPATION IN TRAINING PROCESS AND FOR AN IMPROVED METHOD IN THE INDIVIDUAL STUDY. DURING THE COURSE THE TEACHER WILL CHECK THE ACQUIRED KNOWLEDGE AND WILL MODULATE THE RHYTHMS AND METHOD OF TEACHING ON THE BASES OF THE ACTUAL CLASSROOM COMPOSITION.

KNOWLEDGE AND UNDERSTANDING: THIS COURSE AIMS TO PROVIDE THE BASIC KNOWLEDGE OF SYMMETRY AND SPECTROSCOPY AND TO PROVIDE THE METHODS TO GET INFORMATION FROM SEVERAL SPECTROSCOPIC TECHNIQUES FOR THE CHARACTERIZATION OF INORGANIC AND METALLORGANIC COMPOUNDS

APPLYING KNOWLEDGE AND UNDERSTANDING: AT THE END OF THE COURSE THE STUDENT WILL BE ABLE TO SOLVE PROBLEMS OF STRUCTURAL ASSIGNMENT BY SPECTROSCOPIC ANALYSIS.

MAKING JUDGMENTS: STUDENTS ARE ENCOURAGED TO LEARN IN A CRITICAL MANNER. DURING THE COURSE EXERCISES WILL PROPOSED. THE TEACHER WILL ENCOURAGE THE STUDENTS WITH QUESTIONS AND DISCUSSIONS ON THE MATTERS OF COURSE.

COMMUNICATION SKILLS: THE TEACHER WILL PROMOTE THE ABILITY TO EXPOSE IN A CLEAR AND STRICT WAY THE CONCEPTS LEARNED DURING THE LESSONS. AT THE END OF THE COURSE THE STUDENT MUST BE ABLE TO PROPERLY EXPLAIN THE ARGUMENTS OF THE COURSE.

LEARNING SKILLS : THE STUDENTS WILL BE PROVIDED WITH APPROPRIATE ADVICE AND INCENTIVES FOR AN ACTIVE PARTICIPATION IN TRAINING PROCESS AND FOR AN IMPROVED METHOD IN THE INDIVIDUAL STUDY. DURING THE COURSE THE TEACHER WILL CHECK THE ACQUIRED KNOWLEDGE AND WILL MODULATE THE RHYTHMS AND METHOD OF TEACHING ON THE BASES OF THE ACTUAL CLASSROOM COMPOSITION.

	Prerequisites
	BASIC KNOWLEDGE OF INORGANIC AND COORDINATION CHEMISTRY

	Contents
	ULTRAVIOLET SPECTROSCOPY - INTRODUCTION TO ULTRAVIOLET SPECTROSCOPY - SPIN-ORBIT COUPLING - SPECTROSCOPIC TERMS - DETERMINATION OF SPECTROSCOPIC STATES FOR DIFFERENT CONFIGURATIONS - SELECTION RULES -SPLITTING OF SPECTROSCOPIC SPECTROSCOPIC - ORGEL DIAGRAMS - RACAH PARAMETERS - TANABE - SUGANO DIAGRAMS - ENLARGEMENT OF THE SPECTRAL LINES - LMCT AND MLCT BANDS – LITERATURE EXAMPLES - PRACTICAL ASPECTS - COMPOSITION AND STABILITY OF THE COMPLEX - JOB AND SCATCHARD METHODS - EXERCISE ON SPECTROSCOPIC SERIES OF COMPLEXES OF COBALT (III) FLUORESCENCE SPECTROSCOPY - INTRODUCTION TO FLUORESCENCE SPECTROSCOPY - JABLONSKI DIAGRAM - KASHA'S RULE - STOKES' SHIFT - MIRROR IMAGE RULE – NON-RADIATIVE DECAY PROCESSES - VIBRATIONAL RELAXATION - INTERNAL CONVERSION - INTERSYSTEM CONVERSION – FLUORESCENCE QUENCHING - KINETIC PHENOMENA OF RELAXATION PROCESSES - QUANTUM YIELD AND LIFE TIME - FLUORESCENT PROBES - EXCIMER AND EXCIPLEXES - INSTRUMENTATION - INTENSITY OF FLUORESCENCE - SPECTRAL ARTIFACTS - SOLVATACROMISM - FRET - APPLICATIONS OF FRET - LUMINESCENCE IN THE COMPLEXES OF TRANSITION METALS - EXAMPLES OF LITERATURE ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY - PRINCIPLES - THE G FACTOR - EPR SPECTROMETER - SELECTION RULES - HYPERFINE COUPLING - PREDICTION OF THE MULTIPLICITY OF SPECTRAL LINES - HYPERFINE COUPLING - DIPOLE-DIPOLE INTERACTION - CONTACT INTERACTION - POLARIZATION OF THE SPIN - RADICALS - PARAMETERS FOR THE SPECTRA ESR OF ORGANIC RADICALS - SPIN TRAPPING - EPR OF THE COMPLEXES OF TRANSITION METALS - ANISOTROPY OF G FACTOR - TYPE AND NUMBER OF TRANSITIONS - ZERO-FIELD SPLITTING - KRAMER RULE - PRACTICAL ASPECTS NUCLEAR MAGNETIC RESONANCE OF COMPLEXES OF PARAMAGNETIC NUCLEAR MAGNETIC RESONANCE IN THE TRANSITION METAL COMPLEXES - HYPERFINE SHIFT - SCALAR INTERACTION - DIPOLAR INTERACTION - ASSIGNMENT OF RESONANCES - PRACTICAL ASPECTS NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY OF INORGANIC COMPOUNDS - NUCLEAR SPIN - NUCLEAR MAGNETIC MOMENT - LARMORN PROCESSION – POPULATION OF THE LEVELS AND MACROSCOPIC MAGNETIZATION - INTERACTION OF MACROSCOPIC MAGNETIZATION WITH A SECOND EXTERNAL MAGNETIC FIELD - LONGITUDINAL AND TRANSVERSE MAGNETIZATION - FID - THE ROTATING FRAME – 90 AND 180 PULSES - RELAXATION - MECHANISMS OF RELAXATION - MEASUREMENT OF RELAXATION TIME - THE SPIN-ECHO SEQUENCE - EXPERIMENTS WITH IMPULSES - DIGITAL RESOLUTION AND ACQUISITION TIME - ZERO FILLING - RESOLUTION ENHANCEMENT - APODIZATION - DOUBLE RESONANCE EXPERIMENTS - NOE- INEPT - DEPT - EXCHANGE - LINE SHAPE ANALYSIS – NMR TITRATION – OBSERVABILITY OF METAL NUCLEI - TUNING AND MATCHING - QUADRUPOLE - STRUCTURAL INFORMATION OF INORGANIC AND ORGANOMETALLIC DEDUCTIBLE BY SPECTRAL PARAMETERS - PRACTICAL ASPECTS

Contents

ULTRAVIOLET SPECTROSCOPY
- INTRODUCTION TO ULTRAVIOLET SPECTROSCOPY - SPIN-ORBIT COUPLING - SPECTROSCOPIC TERMS - DETERMINATION OF SPECTROSCOPIC STATES FOR DIFFERENT CONFIGURATIONS - SELECTION RULES -SPLITTING OF SPECTROSCOPIC SPECTROSCOPIC - ORGEL DIAGRAMS - RACAH PARAMETERS - TANABE - SUGANO DIAGRAMS - ENLARGEMENT OF THE SPECTRAL LINES - LMCT AND MLCT BANDS – LITERATURE EXAMPLES - PRACTICAL ASPECTS - COMPOSITION AND STABILITY OF THE COMPLEX - JOB AND SCATCHARD METHODS - EXERCISE ON SPECTROSCOPIC SERIES OF COMPLEXES OF COBALT (III)

FLUORESCENCE SPECTROSCOPY
- INTRODUCTION TO FLUORESCENCE SPECTROSCOPY - JABLONSKI DIAGRAM - KASHA'S RULE - STOKES' SHIFT - MIRROR IMAGE RULE – NON-RADIATIVE DECAY PROCESSES - VIBRATIONAL RELAXATION - INTERNAL CONVERSION - INTERSYSTEM CONVERSION – FLUORESCENCE QUENCHING - KINETIC PHENOMENA OF RELAXATION PROCESSES - QUANTUM YIELD AND LIFE TIME - FLUORESCENT PROBES - EXCIMER AND EXCIPLEXES - INSTRUMENTATION - INTENSITY OF FLUORESCENCE - SPECTRAL ARTIFACTS - SOLVATACROMISM - FRET - APPLICATIONS OF FRET - LUMINESCENCE IN THE COMPLEXES OF TRANSITION METALS - EXAMPLES OF LITERATURE

ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY
- PRINCIPLES - THE G FACTOR - EPR SPECTROMETER - SELECTION RULES - HYPERFINE COUPLING - PREDICTION OF THE MULTIPLICITY OF SPECTRAL LINES - HYPERFINE COUPLING - DIPOLE-DIPOLE INTERACTION - CONTACT INTERACTION - POLARIZATION OF THE SPIN - RADICALS - PARAMETERS FOR THE SPECTRA ESR OF ORGANIC RADICALS - SPIN TRAPPING - EPR OF THE COMPLEXES OF TRANSITION METALS - ANISOTROPY OF G FACTOR - TYPE AND NUMBER OF TRANSITIONS - ZERO-FIELD SPLITTING - KRAMER RULE - PRACTICAL ASPECTS

NUCLEAR MAGNETIC RESONANCE OF COMPLEXES OF PARAMAGNETIC
NUCLEAR MAGNETIC RESONANCE IN THE TRANSITION METAL COMPLEXES - HYPERFINE SHIFT - SCALAR INTERACTION - DIPOLAR INTERACTION - ASSIGNMENT OF RESONANCES - PRACTICAL ASPECTS

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY OF INORGANIC COMPOUNDS
- NUCLEAR SPIN - NUCLEAR MAGNETIC MOMENT - LARMORN PROCESSION – POPULATION OF THE LEVELS AND MACROSCOPIC MAGNETIZATION - INTERACTION OF MACROSCOPIC MAGNETIZATION WITH A SECOND EXTERNAL MAGNETIC FIELD - LONGITUDINAL AND TRANSVERSE MAGNETIZATION - FID - THE ROTATING FRAME – 90 AND 180 PULSES - RELAXATION - MECHANISMS OF RELAXATION - MEASUREMENT OF RELAXATION TIME - THE SPIN-ECHO SEQUENCE - EXPERIMENTS WITH IMPULSES - DIGITAL RESOLUTION AND ACQUISITION TIME - ZERO FILLING - RESOLUTION ENHANCEMENT - APODIZATION - DOUBLE RESONANCE EXPERIMENTS - NOE- INEPT - DEPT - EXCHANGE - LINE SHAPE ANALYSIS – NMR TITRATION – OBSERVABILITY OF METAL NUCLEI - TUNING AND MATCHING - QUADRUPOLE - STRUCTURAL INFORMATION OF INORGANIC AND ORGANOMETALLIC DEDUCTIBLE BY SPECTRAL PARAMETERS - PRACTICAL ASPECTS

	Teaching Methods
	LECTURES

	Verification of learning
	ORAL EXAMINATION

	Texts
	D. C. HARRIS, M. D. BERTOLUCCI "SYMMETRY AND SPECTROSCOPY" DOVER PUBLICATIONS- NEW YORK R. S. DRAGO “PHYSICAL METHODS IN INORGANIC CHEMISTRY” REINHOLD PUBLISHING CORPORATION – NEW YORK J. A. IGGO “NMR: SPECTROSCOPY IN INORGANIC CHEMISTRY” OXFORD SCIENCE PUBLICATIONS