Scienze Ambientali | ENVIRONMENTAL PHYSICAL CHEMISTRY

cod. 0522400005

ENVIRONMENTAL PHYSICAL CHEMISTRY

	0522400005
	DIPARTIMENTO DI CHIMICA E BIOLOGIA "ADOLFO ZAMBELLI"

	ENVIRONMENTAL SCIENCES
	2015/2016

PERCORSO COMUNE

	OBBLIGATORIO
	YEAR OF COURSE 1
	YEAR OF DIDACTIC SYSTEM 2010
	SECONDO SEMESTRE

TEACHING UNITS

SSD	CFU	HOURS	ACTIVITY	TYPE OF ACTIVITY
CHIM/02	5	40	LESSONS	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS
CHIM/02	1	12	LAB	COMPULSORY SUBJECTS, CHARACTERISTIC OF THE CLASS

	Objectives
	UNDERSTANDING THE BASIC LAWS OF THERMODYNAMICS. KNOWING HOW TO RESOLVE NUMERICAL TESTS CONCERNING THE CHEMICAL AND PHASE EQUILIBRIUM.

	Prerequisites
	A BASIC KNOWLEDGE OF GENERAL CHEMISTRY, MATHEMATICS AND PHYSICS.

	Contents
	KINETIC THEORY OF GASES. DISTRIBUTION OF MOLECULAR VELOCITIES. DIFFUSION AND EFFUSION. FREE MEAN PATH AND MOLECULAR COLLISIONS. THERMODYNAMIC SYSTEM; THERMODYNAMIC EQUILIBRIUM. STATE EQUATIONS. REAL GASES. WORK AND HEAT; REVERSIBLE TRANSFORMATIONS. INTERNAL ENERGY, FIRST LAW OF THERMODYNAMIC. ENTHALPY. HEAT CAPACITIES. THERMO-CHEMISTRY. STANDARD STATE. HESS LAW. SECOND LAW OF THERMODYNAMIC. ENTHROPY. GIBBS ENERGY. PHASE EQUILIBRIUM. STATE DIAGRAM. PARTIAL MOLAR PROPERTIES; CHEMICAL POTENTIAL. IDEAL SOLUTIONS AND RAOULT LAW. IDEAL DILUTE SOLUTION AND HENRY LAW. NON IDEAL SOLUTIONS. COLLIGARIVE PROPERTIES. P/X E T/X DIAGRAMS. FRACTIONAL DISTILLATION. AZEOTROPE. EUTECTIC. CHEMICAL EQUILIBRIUM. STANDARD GIBBS ENERGY OF REACTION; EQUILIBRIUM CONSTANT. INFLUENCE OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT. PRESSURE EFFECT ON THE EQUILIBRIUM CONSTANT.

KINETIC THEORY OF GASES. DISTRIBUTION OF MOLECULAR VELOCITIES. DIFFUSION AND EFFUSION. FREE MEAN PATH AND MOLECULAR COLLISIONS. THERMODYNAMIC SYSTEM; THERMODYNAMIC EQUILIBRIUM. STATE EQUATIONS. REAL GASES. WORK AND HEAT; REVERSIBLE TRANSFORMATIONS. INTERNAL ENERGY, FIRST LAW OF THERMODYNAMIC. ENTHALPY. HEAT CAPACITIES. THERMO-CHEMISTRY. STANDARD STATE. HESS LAW. SECOND LAW OF THERMODYNAMIC. ENTHROPY. GIBBS ENERGY. PHASE EQUILIBRIUM. STATE DIAGRAM. PARTIAL MOLAR PROPERTIES; CHEMICAL POTENTIAL. IDEAL SOLUTIONS AND RAOULT LAW. IDEAL DILUTE SOLUTION AND HENRY LAW. NON IDEAL SOLUTIONS. COLLIGARIVE PROPERTIES. P/X E T/X DIAGRAMS. FRACTIONAL DISTILLATION. AZEOTROPE. EUTECTIC. CHEMICAL EQUILIBRIUM. STANDARD GIBBS ENERGY OF REACTION; EQUILIBRIUM CONSTANT. INFLUENCE OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT. PRESSURE EFFECT ON THE EQUILIBRIUM CONSTANT.